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giovedì 21 novembre 2013

GRANITO SU MARTE (come avranno fatto gli Shardana a portarcelo?)

Evidence found for granite on Mars


Researchers now have stronger evidence of granite on Mars and a new theory for how the granite -- an igneous rock common on Earth -- could have formed there, according to a new study. The findings suggest a much more geologically complex Mars than previously believed.

Evidence found for granite on Mars
NASA's Mars Reconnaissance Orbiter is providing new spectral "windows" into the diversity of Martian surface materials. Here in a volcanic caldera, bright magenta outcrops have a distinctive feldspar-rich composition [Credit: NASA/JPL/JHUAPL/MSSS]
Large amounts of a mineral found in granite, known as feldspar, were found in an ancient Martian volcano. Further, minerals that are common in basalts that are rich in iron and magnesium, ubiquitous on Mars, are nearly completely absent at this location. The location of the feldspar also provides an explanation for how granite could have formed on Mars. Granite, or its eruptive equivalent, rhyolite, is often found on Earth in tectonically active regions such as subduction zones. This is unlikely on Mars, but the research team concluded that prolonged magmatic activity on Mars can also produce these compositions on large scales.

"We're providing the most compelling evidence to date that Mars has granitic rocks," said James Wray, an assistant professor in the School of Earth and Atmospheric Sciences at the Georgia Institute of Technology and the study's lead author.

The research was published November 17 in the Advance Online Publication of the journal Nature Geoscience. The work was supported by the NASA Mars Data Analysis Program.

For years Mars was considered geologically simplistic, consisting mostly of one kind of rock, in contrast to the diverse geology of Earth. The rocks that cover most of Mars's surface are dark-colored volcanic rocks, called basalt, a type of rock also found throughout Hawaii for instance.

But earlier this year, the Mars Curiosity rover surprised scientists by discovering soils with a composition similar to granite, a light-colored, common igneous rock. No one knew what to make of the discovery because it was limited to one site on Mars.

The new study bolsters the evidence for granite on Mars by using remote sensing techniques with infrared spectroscopy to survey a large volcano on Mars that was active for billions of years. The volcano is dust-free, making it ideal for the study. Most volcanoes on Mars are blanketed with dust, but this volcano is being sand-blasted by some of the fastest-moving sand dunes on Mars, sweeping away any dust that might fall on the volcano. Inside, the research team found rich deposits of feldspar, which came as a surprise.

"Using the kind of infrared spectroscopic technique we were using, you shouldn't really be able to detect feldspar minerals, unless there's really, really a lot of feldspar and very little of the dark minerals that you get in basalt," Wray said.

The location of the feldspar and absence of dark minerals inside the ancient volcano provides an explanation for how granite could form on Mars. While the magma slowly cools in the subsurface, low density melt separates from dense crystals in a process called fractionation. The cycle is repeated over and over for millennia until granite is formed. This process could happen inside of a volcano that is active over a long period of time, according to the computer simulations run in collaboration with Josef Dufek, who is also an associate professor in the School of Earth and Atmospheric Sciences at Georgia Tech.

"We think some of the volcanoes on Mars were sporadically active for billions of years," Wray said. "It seems plausible that in a volcano you could get enough iterations of that reprocessing that you could form something like granite."

This process is sometimes referred to as igneous distillation. In this case the distillation progressively enriches the melt in silica, which makes the melt, and eventual rock, lower density and gives it the physical properties of granite.

"These compositions are roughly similar to those comprising the plutons at Yosemite or erupting magmas at Mount St. Helens, and are dramatically different than the basalts that dominate the rest of the planet," Dufek said.

Another study published in the same edition of Nature Geoscience by a different research team offers another interpretation for the feldspar-rich signature on Mars. That team, from the European Southern Observatory and the University of Paris, found a similar signature elsewhere on Mars, but likens the rocks to anorthosite, which is common on the moon. Wray believes the context of the feldspar minerals inside of the volcano makes a stronger argument for granite. Mars hasn't been known to contain much of either anorthosite or granite, so either way, the findings suggest the Red Planet is more geologically interesting than before.

"We talk about water on Mars all the time, but the history of volcanism on Mars is another thing that we'd like to try to understand," Wray said. "What kinds of rocks have been forming over the planet's history? We thought that it was a pretty easy answer, but we're now joining the emerging chorus saying things may be a little bit more diverse on Mars, as they are on Earth."

This research is supported by the NASA Mars Data Analysis Program under award NNX13AH80G. Any conclusions or opinions are those of the authors and do not necessarily represent the official views of the sponsoring agencies.

Author: Brett Israel | Source: Georgia Institute of Technology [November 18, 2013]

giovedì 10 ottobre 2013

Scarabeo Egizio, materiale: Cometa

Il primo frammento di cometa rinvenuto sulla terra.


10 ottobre 2013
Redazione Tiscali



E' stato prodotto dall'esplosione di una cometa avvenuta 28 milioni di anni fa sull'Egitto, il vetro giallo incastonato in uno dei gioielli della mummia di Tutankhamon. E' la prima testimonianza in assoluto dell'impatto di una cometa nell'atmosfera terrestre.
Il frammento è stato lucidato e scolpito dagli antichi Egizi, che lo hanno modellato come uno scarabeo, ma la sua origine è sicuramente cosmica: lo dimostra la ricerca in via di pubblicazione sulla rivista Earth and Planetary Science Letters (EPSL) e condotta dal gruppo internazionale di geologi, fisici ed astronomi coordinato da Jan Kramers, dell'Università sudafricana di Johannesburg.
Tra i ricercatori c'è anche l'italiano Marco Andreoli, della South African Nuclear Energy Corporation. Secondo la ricostruzione dei ricercatori l'esplosione della cometa, avvenuta sul deserto del Sahara, riscaldò la sabbia portandola alla temperatura di circa 2.000 gradi. Si formò in questo modo un'enorme quantità di vetro di silice giallo, sparso su una su una superficie di oltre 6.000 chilometri quadrati. Uno di questi frammenti è stato modellato e incastonato nel gioiello del faraone.
Ad attirare inizialmente l'attenzione degli studiosi è stata una pietra scura trovata anni fa da un geologo egiziano: analizzata nuovamente adesso risulta essere tutt'altro che un comune meteorite: è quello che resta del nucleo della cometa esplosa sulla Terra milioni di anni fa.
L'esplosione ha anche prodotto microscopici diamanti. "I diamanti normalmente si formano nelle viscere della terra dove la pressione è alta - osserva Kramers - ma è anche possibile generare una pressione molto elevata attraverso una forte esplosione''. I ricercatori sono convinti che la scoperta del materiale prodotto dalla cometa permetterà di aggiungere tasselli preziosi per ricostruire la storia del Sistema Solare.
ARTICOLO ORIGINALE (da EPSL):





Unique chemistry of a diamond-bearing pebble from the Libyan Desert Glass strewnfield, SW Egypt: Evidence for a shocked comet fragment


  • a Department of Geology, University of Johannesburg, Auckland Park 2006, South Africa
  • b NECSA, PO Box 582, Pretoria 0001, South Africa
  • c School of Geosciences, University of the Witwatersrand, PO Box 3, Wits 2050, South Africa
  • d Council for Geoscience, PO Box 112, Pretoria 0001, South Africa
  • e AECI and AVENG Cosmic Dust Laboratory, School of Computational and Applied Mathematics, University of the Witwatersrand, PO Box 60, Wits 2050, South Africa
  • f Department of Geological Sciences, University of Cape Town, Rondebosch 7701, South Africa
  • g Element Six (Pty) Ltd, Springs 1559, South Africa
  • h LPMCN, Université Lyon 1 and CNRS, UMR 5586, F-69622 Villeurbanne, France




Highlights

•
A carbonaceous stone found in the Libyan Desert Glass strewnfield was studied.
•
It contains sub-micrometer diamonds in an amorphous, carbon-dominated matrix.
•
Carbon isotope data (δ13C∼0) do not fit terrestrial coal or carbonaceous chondrites.
•
Argon, Kr and Xe isotope data show extraterrestrial origin different from chondrites.
•
We propose that the stone is a fragment of a comet nucleus, shocked on impact.


Abstract

We have studied a small, very unusual stone, here named “Hypatia”, found in the area of southwest Egypt where an extreme surface heating event produced the Libyan Desert Glass 28.5 million years ago. It is angular, black, shiny, extremely hard and intensely fractured. We report on exploratory work including X-ray diffraction, Raman spectroscopy, transmission electron microscopy, scanning electron microscopy with EDS analysis, deuteron nuclear reaction analysis, C-isotope and noble gas analyses. Carbon is the dominant element in Hypatia, with heterogeneous O/C and N/C ratios ranging from 0.3 to 0.5 and from 0.007 to 0.02, respectively. The major cations of silicates add up to less than 5%. The stone consists chiefly of apparently amorphous, but very hard carbonaceous matter, in which patches of sub-μm diamonds occur. δ13C values (ca. 0‰) exclude an origin from shocked terrestrial coal or any variety of terrestrial diamond. They are also higher than the values for carbonaceous chondrites but fall within the wide range for interplanetary dust particles and comet 81P/Wild2 dust. In step heating, 40Ar/36Ar ratios vary from 40 to the air value (298), interpreted as a variable mixture of extraterrestrial and atmospheric Ar. Isotope data of Ne, Kr and Xe reveal the exotic noble gas components G and P3 that are normally hosted in presolar SiC and nanodiamonds, while the most common trapped noble gas component of chondritic meteorites, Q, appears to be absent. An origin remote from the asteroid belt can account for these features.
We propose that the Hypatia stone is a remnant of a cometary nucleus fragment that impacted after incorporating gases from the atmosphere. Its co-occurrence with Libyan Desert Glass suggests that this fragment could have been part of a bolide that broke up and exploded in the airburst that formed the Glass. Its extraordinary preservation would be due to its shock-transformation into a weathering-resistant assemblage.


Keywords

  • Libyan Desert Glass;
  • shock diamonds;
  • extraterrestrial carbonaceous matter;
  • carbon isotopes;
  • noble gas isotopes;
  • comet nucleus


Figures and tables from this article:
Full-size image (137 K)
Fig. 1. A: Macrophotograph of sample Hyp-1, the largest among a group of subsamples split from the primary Hypatia stone. Note secondary desert varnish coating and a thin open fracture on the left side (white arrows). B, C: scanning electron microscope backscattered electron images of a fracture surface on a second subsample (Hyp-2). In B, dark material is richer in oxygen than light material. In C, light material is Fe–Cr–Ni alloy. Working distance: B, 15.1 mm; C, 14.4 mm. Detectors: B: Everhardt–Thornley; C: Dual backscatter. High voltage: B, 30 kV; C, 20 kV. D–G: element maps for C, Al, Fe, S (element symbols in left top corners, lighter shades indicate higher concentration) produced on a polished section of Hypatia (Hyp-3) using the TeScan instrument (20 kV). Carbon dominates the matrix (D). Aluminum marks secondary clay minerals formed on cracks (E). In F and G, note the close coincidence of Fe with S. Equal abundances signal pyrrhotite.

Full-size image (53 K)
Fig. 2. A: optical image of an area of the polished section of Hyp-3. B: Raman spectral map of the same area produced by the WiTek Raman microscope. Light and dark grey patches correspond to the top and bottom spectra shown in C, respectively (variable baseline removed). Bottom spectrum in C shows both D and G bands indicating a carbon structure with both sp2 and sp3 bonds, whereas in the top spectrum the G band is almost absent and the D band is very sharp, indicating diamond. Thus light grey areas in B are dominated by diamond. D: bright-field transmission electron microscope image of a grain from Hyp-3. The nm-scale cracks and voids seen are not an artifact of the sample preparation as they are not observed in similar imagery on terrestrial diamond samples. “Dark” specs are cubic diamond domains with orientations causing electron diffraction. A selected area diffraction pattern of this region (Supplementary Fig. 2) shows several rings, indicating a fine polycrystalline aggregate. A line calibrated profile of the selected area diffraction intensity is shown in Supplementary Fig. 3. Supplementary Table 3 shows the d-spacings corresponding to the first 5 rings, and the corresponding diffraction planes in cubic diamond.

Full-size image (13 K)
Fig. 3. O/C ratios, N/C ratios (determined both by SEM energy dispersive analysis and nuclear reaction analysis) and δ13C(PDB) values of Hypatia matrix matter (see Table 1, Supplementary Table 2), compared to terrestrial and extraterrestrial sample sets: coal (,  and ), bulk carbonaceous chondrites (Kerridge, 1985), chondritic IOM (Alexander et al., 2007), carbonados (,  and ), impact-produced diamonds (Koeberl et al., 1997), Comet Halley (Greenberg and Li, 1999), Comet 81P-Wild 2 dust (, , ,  and ), interplanetary dust particles ( and ), Earthʼs mantle (Sharp, 2007). All bars include the uncertainty limits. For O/C and N/C ratios of Hypatia, “dark” and “pale” spots refer to Fig. 1B. For δ13C values, “A” and “B” imply an ultrasonic treatment in ethanol only, whereas “HCl” denotes a cleaning in hot, dilute HCl. Stippled line for carbonados δ13C represents rare occurrences of heavier values (Shelkov et al., 1997).

Full-size image (48 K)
Fig. 4. Noble gas abundances (cc stp/g) for heating steps from Hypatia fragments Hyp-7, -9, -10 and -11, normalized to Earth concentrations (total atmospheric inventory divided by the Earthʼs mass). Heating step temperatures are shown in °C. For comparison, the atmosphere—normalized relative solar abundance pattern (summarized by Wieler, 2002; arbitrarily positioned to fit in the frame) is shown in (C).

Full-size image (18 K)
Fig. 5. 40Ar/36Ar ratios versus amount of 36Ar released at individual incremental heating steps (temperatures shown in °C). Dashed lines “Atm”: Earthʼs atmosphere. f36ArET, the extraterrestrial fraction of 36Ar, is scaled on the right hand side of each panel; the bulk value of f36ArET listed in the panels is the weighted average of the step values.

Full-size image (6 K)
Fig. 6. Conventional three-isotope plot for neon extracted from a large (3.1 mg) fragment (Hyp-12) in broad temperature steps (not corrected for blank (b) which is of atmospheric composition; data in Supplementary Table 6), compared with atmospheric (A, Pepin and Porcelli, 2002) and the meteoritic trapped components Q, P3, HL and G (summarized by Ott, 2002, and discussed in the text). No sample gas from the 1900 °C step could be measured, as a huge eruption of gas occurred (larger than in Hyp-11) which had to be pumped out immediately to prevent damage. A remnant of Ar from this gas, trapped on a cold finger, proved to be of atmospheric composition.

Full-size image (73 K)
Fig. 7. Three-isotope plots for Kr and Xe from the heating steps of four Hypatia fragments, shown with 2σ error bars, compared with atmospheric and various extraterrestrial isotope compositions. Narrow-dashed arrows with double heads show direction of mass-dependent fractionation enriching heavy (f+) or light (f−) isotopes. Labels on data points deviating strongly from the main populations give the Hyp-number and the step temperature in °C (referring to Supplementary Tables 7 and 8). A: Krypton data. “Common” comprises isotopic compositions of atmospheric, solar wind, Q and P3 components discussed in the text, as summarized by Ott (2002), Wieler (2002) and Pepin and Porcelli (2002), which are not resolved at this scale. Only the HL and G components are clearly different. Broad-dashed arrow points to G composition outside the plot. Grey area is 95% confidence envelope of a York fit through the Hypatia data only (not forced through “common”). B: 128Xe/132Xe vs. 136Xe/132Xe, Atm: atmosphere (Pepin and Porcelli, 2002), Sol: solar wind (Wieler, 2002). Isotopic compositions of chondritic noble gas components as for A. Broad-dashed arrows with coordinates point to the components outside the plot. Grey area as in A. C: 129Xe/132Xe vs. 136Xe/132Xe. The dashed triangle (apices Atm, Q and arrows pointing to distant G component) contains most of the data, suggesting 3-component mixing as discussed in the text.

mercoledì 12 giugno 2013

Sostanze chimiche che sottendono la vita, su Marte.

Martian clay contains chemical implicated in the origin of life


Researchers from the University of Hawaii at Manoa NASA Astrobiology Institute (UHNAI) have discovered high concentrations of boron in a Martian meteorite. When present in its oxidized form (borate), boron may have played a key role in the formation of RNA, one of the building blocks for life.

Martian clay contains chemical implicated in the origin of life
Electron microscope image showing the 700-million-year-old Martian clay veins containing boron (100 µm = one tenth of a millimeter) [Credit: Institute for Astronomy at the University of Hawaii at Manoa]
The Antarctic Search for Meteorites team found the Martian meteorite used in this study in Antarctica during its 2009-2010 field season. The minerals it contains, as well as its chemical composition, clearly show that it is of Martian origin.

Using the ion microprobe in the W. M. Keck Cosmochemistry Laboratory at UH, the team was able to analyze veins of Martian clay in the meteorite. After ruling out contamination from Earth, they determined boron abundances in these clays are over ten times higher than in any previously measured meteorite.

"Borates may have been important for the origin of life on Earth because they can stabilize ribose, a crucial component of RNA. In early life RNA is thought to have been the informational precursor to DNA," said James Stephenson, a UHNAI postdoctoral fellow.

RNA may have been the first molecule to store information and pass it on to the next generation, a mechanism crucial for evolution. Although life has now evolved a sophisticated mechanism to synthesize RNA, the first RNA molecules must have been made without such help. One of the most difficult steps in making RNA nonbiologically is the formation of the RNA sugar component, ribose. Previous laboratory tests have shown that without borate the chemicals available on the early Earth fail to build ribose. However, in the presence of borate, ribose is spontaneously produced and stabilized.

This work was born from the uniquely interdisciplinary environment of UHNAI. The lead authors on the paper, Stephenson, an evolutionary biologist, and Lydia Hallis, a cosmochemist who is also a UHNAI postdoctoral fellow, first came up with the idea over an after-work beer. "Given that boron has been implicated in the emergence of life, I had assumed that it was well characterized in meteorites," said Stephenson. "Discussing this with Dr. Hallis, I found out that it was barely studied. I was shocked and excited. She then informed me that both the samples and the specialized machinery needed to analyze them were available at UH."

On our planet, borate-enriched salt, sediment and clay deposits are relatively common, but such deposits had never previously been found on an extraterrestrial body. This new research suggests that when life was getting started on Earth, borate could also have been concentrated in deposits on Mars.

The significance goes beyond an interest in the red planet, as Hallis explains: "Earth and Mars used to have much more in common than they do today. Over time, Mars has lost a lot of its atmosphere and surface water, but ancient meteorites preserve delicate clays from wetter periods in Mars' history. The Martian clay we studied is thought to be up to 700 million years old. The recycling of the Earth's crust via plate tectonics has left no evidence of clays this old on our planet; hence Martian clays could provide essential information regarding environmental conditions on the early Earth."

The presence of ancient borate-enriched clays on Mars implies that these clays may also have been present on the early Earth. Borate-enriched clays such as the ones studied here may have represented chemical havens in which one of life's key molecular building blocks could form.

UHNAI is a research center that links the biological, chemical, geological, and astronomical sciences to better understand the origin, history, distribution, and role of water as it relates to life in the universe.

The work was published on June 6 in PLOS ONE.

Source: Institute for Astronomy at the University of Hawaii at Manoa [June 10, 2013]